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- W2020032555 abstract "A new method for calculating the partition function of real gases is developed and applied to a system of point charges without repulsive core, e.g., a fully ionized hydrogen gas. The electrostatic energy U of the total system is represented as a function of the Fourier coefficients, As, of the particle density, and the configuration integral is evaluated by direct integration in the function space which is generated by the As. To this purpose, the As are treated as stochastic variables characterized by a multivariate probability density whose determination represents a major part of this paper. The potential of mean force, W(r) is found equal to the average Debye-Hückel potential, (Z2e2r) exp (−rh), (Ze = ionic charge, h = Debye shielding length). The radial distribution function g(r) is determined as g(r) = exp[−W(r)kT], and the part of U which is proportional to the total particle number N is found to be equal to the Debye-Hückel energy." @default.
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- W2020032555 date "1962-01-01" @default.
- W2020032555 modified "2023-09-26" @default.
- W2020032555 title "New method for determining the thermodynamic functions of dense gases and plasmas" @default.
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- W2020032555 doi "https://doi.org/10.1016/0003-4916(62)90257-9" @default.
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