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- W2020038105 abstract "Abstract The uniform interpretation of the crystal field effect in three different U(5 + ) fluoride compounds: CsUF6, α-UF5 and β-UF5 within the angular overlap model (AOM) is given. Some characteristic relations between the AOM parameters and their distance dependencies resulting from ab inltio calculations are introduced and examined from a phenomenological point of view. The traditional simplest approach with only one independent parameter, i.e.eσ with eπ:eσ = 0.32 and eδ = 0, is shown to provide a consistent interpretation of the crystal field effect of the whole class of the compounds. The parameters obtained for one compound are easily and successfully extrapolated to others. The specificity and importance of the eδ parameter for 5f1 systems is discussed." @default.
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- W2020038105 title "Uniform angular overlap model interpretation of the crystal field effect in U(5 + ) fluoride compounds" @default.
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- W2020038105 doi "https://doi.org/10.1016/0022-5088(90)90020-k" @default.
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