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- W2020042377 abstract "Abstract A new phase was found in the bismuth-rich portion of the system Bi2O3Ho2O3. This phase formed a solid-solution Bi2−2xHo2xO3 (x=0.205–0.245 at 650°C) having a Bi0.765Sr0.235O1.383-type layered structure with hexagonal symmetry, and showed high oxide-ion conduction. Thermal analysis, isothermal heat treatments and electrical conductivity measurements revealed that the hexagonal phase transformed reversibly into a high-temperature face-centered cubic phase which is known as extrinsic δ-Bi2O3 stabilized by Ho2O3. The hexagonal-cubic transformation temperature varied from 715° to 735°C depending on the composition x. Thus, the cubic phase existed stably only above these transition temperatures, so that the known stabilized δ phase with Ho2O3 was metastable at lower temperatures. The oxide-ion conductivities of both hexagonal and cubic phases were measured and compared. Phase relations of the δ phase “stabilized” by other lanthanoid oxides are discussed." @default.
- W2020042377 created "2016-06-24" @default.
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- W2020042377 date "1989-04-01" @default.
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- W2020042377 title "Phase relations of hexagonal and cubic phases in holmia-doped bismuth sesquioxide, Bi2−2xHo2xO3 (x=0.205–0.245)" @default.
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- W2020042377 doi "https://doi.org/10.1016/0167-2738(89)90427-x" @default.
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