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- W2020046495 abstract "The hydrolysis of ethyl acetate in aqueous solution over various solid acid catalysts was investigated. The activity of high-silica zeolites (H-ZSM-5, dealuminated H-mordenite) was moderate, while that of silica-alumina, nondealuminated H-mordenite, and H-Y zeolite was very small. Notably, the activity of H-ZSM-5 (SiAl = 47) was high and about 40% of that of the cation exchange resin. The H-ZSM-5 had acid sites whose strength was −5.6 < H0 ≦ −3.0 in water. The higher SiAl atomic ratio provided a more hydrophobic property on the catalytic surface, which, therefore, showed better affinity for organic materials than water. However, too high a SiAl atomic ratio resulted in the decrease in the activity, because the acid sites decreased in number." @default.
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- W2020046495 date "1981-11-01" @default.
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- W2020046495 title "Catalytic application of hydrophobic properties of high-silica zeolites I. Hydrolysis of ethyl acetate in aqueous solution" @default.
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- W2020046495 doi "https://doi.org/10.1016/0021-9517(81)90073-7" @default.
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