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- W2020063856 abstract "Automated carbon-13 nuclear magnetic resonance spectroscopy of saccharides from wheat serially harvested through one growing season showed variation of glucose, fructose, sucrose and maltose similar to previous analyses. In a diurnal series glucose and fructose concentrations fluctuated periodically but were relatively unaffected by light and dark. Qualitative 13C-NMR showed myo-inositol, glycerol, 1-kestose, 6-kestose, and glucofructans with glucose: fructose ratios up to 1:12. With increasing chain length there were increasing proportions of 6–2 over 1–2 linkages. Sugars previously reported but not found here included xylose, arabinose, mannose, galactose, raffinose, fructosyl raffinose, stachyose, melecitose and maltotriose.Bestimmung der Saccharide des sich entwickelnden Weizenkorns durch 13C-NMR-Spektroskopie. Die automatische 13C-Kernresonanzspektroskopie der Saccharide von Weizen, der wahrend einer Wachstumsperiode regelmasig geerntet wurde, zeigte ahnlich wie bei fruheren Untersuchungen Veranderungen hinsichtlich des Glucose-, Fructose-, Saccharose- und Maltosegehaltes. Bei einer taglich untersuchten Serie schwankten die Glucose- und Fructosekonzentrationen regelmasig, aber sie waren relativ unbeeinflust durch Licht und Dunkelheit. Durch qualitative 13C-NMR konnten myo-Inositol, Glycerol, 1-Kestose, 6-Kestose und Glucofructane mit einem Glucose: Fructose-Verhaltnis bis zu 1:12 nachgewiesen werden. Mit wachsender Kettenlange nahmen die 6,2- gegenuber den 1,2-Bindungen zu. Zu den Zuckerarten, die bei fruheren Untersuchungen aber nicht bei den vorliegenden Untersuchungen gefunden worden sind, gehoren Xylose, Arabinose, Mannose, Galactose, Raffinose, Fructosylraffinose, Stachyose, Melicitose und Maltotriose." @default.
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- W2020063856 date "1980-01-01" @default.
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- W2020063856 title "Saccharides of Developing Wheat Grain Determined by13C-NMR Spectroscopy" @default.
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