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- W2020069040 abstract "An attempt is made to formulate a theory of the reaction rate constant for electron scavenging which is valid for high mobility nonpolar liquids. It is proposed that the scavenging mechanism is an electron capture process which is completely analogous to the gas phase process. Application to the liquid state of theory developed for the use in the gas phase requires careful consideration of the relative energies of the quasifree (i.e., V0) and captured states of the electron and it is shown that a reasonable conjecture (that the polarization energy of a scavenger negative ion is the same in all hydrocarbons) allows a semiquantitative correlation of the known experimental results. When the energy of the negative‐ion state of the scavenger in the Franck–Condon region is above the V0 level (e.g., C2H5Br in TMS), the reaction rate is shown to increase with V0, while if the former is below the V0 level (e.g., CCl4 in neopentane), the reaction rate decreases with V0. The temperature dependence of the observed rates is qualitatively consistent with the proposed model." @default.
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- W2020069040 date "1975-06-01" @default.
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- W2020069040 title "On the specific rates for electron scavenging in nonpolar solvents" @default.
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