Matches in SemOpenAlex for { <https://semopenalex.org/work/W2020072458> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2020072458 endingPage "649" @default.
- W2020072458 startingPage "639" @default.
- W2020072458 abstract "Abstract This article extends the composition of linear low‐density polyethylene (LLDPE) resins to that containing 1‐decene comonomer units, and examines the effects of comonomer (type and concentration) to copolymerization and physical properties of LLDPE resins. CGC metallocene technology, under high temperature and high pressure (industrial reaction condition), was used to prepare three types of well‐defined LLDPE copolymers containing 1‐hexene, 1‐octene, and 1‐decene units. They show high molecular weight with narrow molecular weight and composition distributions, comparative catalyst activities, and similar comonomer effects. However, 1‐decene seems to exhibit significantly higher comonomer incorporation than 1‐hexene and 1‐octene, which may be associated with its high boiling point, maintaining liquid phase during the polymerization. The resulting LLDPE copolymers show a clear structure–property relationship. Melting temperature and crystallinity of the copolymer are governed by mole % of comonomer. The increase of branch density linearly decreases the LLDPE melting point and exponential reduction of its crystallinity. On the other hand, the density of the copolymer decreases with the increase of comonomer weight %, which shows a sharp linear relationship in the low comonomer content. The tensile properties of 1‐decene‐based LLDPE are very comparative with those of the commercial LLDPE resins with similar compositions. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 639–649, 2007" @default.
- W2020072458 created "2016-06-24" @default.
- W2020072458 creator A5037260589 @default.
- W2020072458 creator A5052804103 @default.
- W2020072458 creator A5066135125 @default.
- W2020072458 creator A5086609429 @default.
- W2020072458 date "2007-01-09" @default.
- W2020072458 modified "2023-10-16" @default.
- W2020072458 title "Synthesis of new 1‐decene‐based LLDPE resins and comparison with the corresponding 1‐octene‐ and 1‐hexene‐based LLDPE resins" @default.
- W2020072458 cites W1963598338 @default.
- W2020072458 cites W1964357730 @default.
- W2020072458 cites W1981657057 @default.
- W2020072458 cites W1994855513 @default.
- W2020072458 cites W2011077294 @default.
- W2020072458 cites W2012673525 @default.
- W2020072458 cites W2015733311 @default.
- W2020072458 cites W2016009189 @default.
- W2020072458 cites W2044059632 @default.
- W2020072458 cites W2060772218 @default.
- W2020072458 cites W2060963454 @default.
- W2020072458 cites W2075879748 @default.
- W2020072458 cites W2113306216 @default.
- W2020072458 cites W2156331004 @default.
- W2020072458 cites W2162510578 @default.
- W2020072458 cites W2169558498 @default.
- W2020072458 cites W2319108482 @default.
- W2020072458 cites W2322642295 @default.
- W2020072458 doi "https://doi.org/10.1002/pola.21825" @default.
- W2020072458 hasPublicationYear "2007" @default.
- W2020072458 type Work @default.
- W2020072458 sameAs 2020072458 @default.
- W2020072458 citedByCount "39" @default.
- W2020072458 countsByYear W20200724582012 @default.
- W2020072458 countsByYear W20200724582013 @default.
- W2020072458 countsByYear W20200724582014 @default.
- W2020072458 countsByYear W20200724582015 @default.
- W2020072458 countsByYear W20200724582019 @default.
- W2020072458 countsByYear W20200724582020 @default.
- W2020072458 countsByYear W20200724582021 @default.
- W2020072458 crossrefType "journal-article" @default.
- W2020072458 hasAuthorship W2020072458A5037260589 @default.
- W2020072458 hasAuthorship W2020072458A5052804103 @default.
- W2020072458 hasAuthorship W2020072458A5066135125 @default.
- W2020072458 hasAuthorship W2020072458A5086609429 @default.
- W2020072458 hasConcept C15920480 @default.
- W2020072458 hasConcept C159985019 @default.
- W2020072458 hasConcept C185592680 @default.
- W2020072458 hasConcept C188027245 @default.
- W2020072458 hasConcept C192562407 @default.
- W2020072458 hasConcept C2779751980 @default.
- W2020072458 hasConcept C2779964599 @default.
- W2020072458 hasConcept C2780446808 @default.
- W2020072458 hasConcept C2780672802 @default.
- W2020072458 hasConcept C2780953527 @default.
- W2020072458 hasConcept C44228677 @default.
- W2020072458 hasConcept C46275449 @default.
- W2020072458 hasConcept C521977710 @default.
- W2020072458 hasConcept C75841233 @default.
- W2020072458 hasConceptScore W2020072458C15920480 @default.
- W2020072458 hasConceptScore W2020072458C159985019 @default.
- W2020072458 hasConceptScore W2020072458C185592680 @default.
- W2020072458 hasConceptScore W2020072458C188027245 @default.
- W2020072458 hasConceptScore W2020072458C192562407 @default.
- W2020072458 hasConceptScore W2020072458C2779751980 @default.
- W2020072458 hasConceptScore W2020072458C2779964599 @default.
- W2020072458 hasConceptScore W2020072458C2780446808 @default.
- W2020072458 hasConceptScore W2020072458C2780672802 @default.
- W2020072458 hasConceptScore W2020072458C2780953527 @default.
- W2020072458 hasConceptScore W2020072458C44228677 @default.
- W2020072458 hasConceptScore W2020072458C46275449 @default.
- W2020072458 hasConceptScore W2020072458C521977710 @default.
- W2020072458 hasConceptScore W2020072458C75841233 @default.
- W2020072458 hasIssue "4" @default.
- W2020072458 hasLocation W20200724581 @default.
- W2020072458 hasOpenAccess W2020072458 @default.
- W2020072458 hasPrimaryLocation W20200724581 @default.
- W2020072458 hasRelatedWork W1198452196 @default.
- W2020072458 hasRelatedWork W1626723990 @default.
- W2020072458 hasRelatedWork W1963574469 @default.
- W2020072458 hasRelatedWork W2020072458 @default.
- W2020072458 hasRelatedWork W2041793526 @default.
- W2020072458 hasRelatedWork W2062954746 @default.
- W2020072458 hasRelatedWork W2081473651 @default.
- W2020072458 hasRelatedWork W3016445556 @default.
- W2020072458 hasRelatedWork W610493020 @default.
- W2020072458 hasRelatedWork W165384878 @default.
- W2020072458 hasVolume "45" @default.
- W2020072458 isParatext "false" @default.
- W2020072458 isRetracted "false" @default.
- W2020072458 magId "2020072458" @default.
- W2020072458 workType "article" @default.