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- W2020073746 endingPage "13645" @default.
- W2020073746 startingPage "13634" @default.
- W2020073746 abstract "A modular set of phosphite–oxazoline (P,N) ligands has been applied to the title reaction. Excellent ligands have been identified for a range of substrates, including previously challenging terminally disubstituted olefins, where we now have reached enantioselectivities of 99% for a range of substrates. The selectivity is best for minimally functionalized substrates with at least a moderate size difference between geminal groups. A DFT study has allowed identification of the preferred pathway. Computational prediction of enantioselectivities gave very good accuracy." @default.
- W2020073746 created "2016-06-24" @default.
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- W2020073746 creator A5050860412 @default.
- W2020073746 creator A5055299896 @default.
- W2020073746 creator A5075972631 @default.
- W2020073746 date "2011-08-04" @default.
- W2020073746 modified "2023-10-03" @default.
- W2020073746 title "Pyranoside Phosphite–Oxazoline Ligands for the Highly Versatile and Enantioselective Ir-Catalyzed Hydrogenation of Minimally Functionalized Olefins. A Combined Theoretical and Experimental Study" @default.
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- W2020073746 doi "https://doi.org/10.1021/ja204948k" @default.
- W2020073746 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21761872" @default.
- W2020073746 hasPublicationYear "2011" @default.
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