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- W2020078830 abstract "A sensitive electrochemical method was developed for the voltammetric determination of thymine at a composite film-modified electrode 1-phenyl-3-methyl-4-(2-furoyl)-5-pyrazolone (HPMαFP)/polypyrrole (Ppy)/glassy carbon electrode (GCE). The electrochemical parameters of thymine were investigated by cyclic voltammetry and differential pulse voltammetry. In pH = 7.4, one sensitive oxidation peak of thymine with E pa = 0.968 V was observed on the HPMαFP/PPy-modified electrode. The difference of peak potential (∆E pa) was 188 mV lower than that for bare GCE. Compared to the bare GCE and Ppy/GCE, the HPMαFP/Ppy/GCE-modified electrode showed an excellent electrocatalytic effect on the oxidation of thymine and displayed a shift of the oxidation potential in the negative direction with significant increase in the peak current. Under the optimum condition, the concentration calibration range and detection limit are 2 × 10−6–1 × 10−4 and 4.85 × 10−7 M for thymine. This developed method had been applied to the direct determination of thymine in medical pipefish samples with satisfactory results." @default.
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- W2020078830 date "2013-03-06" @default.
- W2020078830 modified "2023-09-27" @default.
- W2020078830 title "Electrochemical methods for determination of thymine in medical pipefish samples based on HPMαFP/Ppy/GCE-modified electrode" @default.
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