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- W2020088161 abstract "Oxanorbornane (7-oxabicyclo[2.2.1]heptane, C 6 H 10 O) resembles other bicycloheptane-like molecules by exhibiting order-disorder transitions in the solid state. Differential scanning calorimetric studies show that five different phases may occur, with hysteresis in the transition temperatures. The vibrational spectra have been examined, and a factor group analysis of the vibrational splittings indicates that the crystal structure of the ordered phase has D 2d symmetry. Activation energies for molecular motions were derived from proton spin-lattice relaxation time measurements.Key words: oxanorbornane, order-disorder, phase transitions." @default.
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- W2020088161 date "1998-10-01" @default.
- W2020088161 modified "2023-09-25" @default.
- W2020088161 title "Spectroscopic and differential scanning calorimetric studies of the phase transitions in oxanorbornane" @default.
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- W2020088161 doi "https://doi.org/10.1139/v98-173" @default.
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