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- W2020094986 abstract "The novel reductant of empirical formula LiCrH2 has been efficiently generated from CrCl3 and 4 equiv of n-butyllithium in THF and can be isolated and characterized as a dark red-brown LiCl-free complex, LiCrH2·THF, by a combination of elemental, gasometric, chemical, IR, and ESR analyses. Without separation from the LiCl byproduct, this reductant is reactive toward a wide range of σ- and π-heteroatomic bonds, effecting reductive cleavage or coupling, oligomerization, and even polymerization of diverse organic substrates." @default.
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- W2020094986 modified "2023-10-09" @default.
- W2020094986 title "Lithium Chromium(I) Dihydride: A Novel Reagent for the Versatile Reductive Metathesis, Reductive Cyclization, Oligomerization, or Polymerization of Diverse Organic Substrates<sup>1</sup>" @default.
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- W2020094986 doi "https://doi.org/10.1021/om991028q" @default.
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