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- W2020098839 abstract "Ion/molecule reactions of electron-impact-induced fragment ions of Co(CO)3NO with 2-chloroethanol, 3-chloro-2-butanone and allyl-X (X = -NH2, -Cl, -Br, -OH, -OC3H5) are reported. The results indicate that the allyl compounds react similarly with Co+ as do their saturated analogs, but as the number of ligand on the Co+ ion increases new reactions are observed which are explained by ligand interactions. The use of metal-containing ions as chemical-ionization reagents for bifunctional organic compounds has also been investigated. The results indicate that the interpretation may be simple if each functional group reacts individually, such as in chlorobutanone, or may not be as simple if the two groups behave as one “new group”, as in 2-chloroethanol." @default.
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- W2020098839 date "1983-04-01" @default.
- W2020098839 modified "2023-09-26" @default.
- W2020098839 title "The gas-phase chemistry of metal and metal-containing ions with multifunctional organic molecules—investigating the utility of such ions as chemical-ionization reagents" @default.
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- W2020098839 doi "https://doi.org/10.1016/0020-7381(83)85079-7" @default.
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