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- W2020100143 abstract "Abstract The photochemical formation of silver metal films from silver salts of high molecular weight carboxylic acids has been studied. On irradiation with a low pressure mercury lamp in wet air at room temperature, the films first became yellow-brown in colour owing to the formation of colloidal silver. After prolonged irradiation, the irradiated surface of the silver salt films of natural high molecular weight carboxylic acids (silver alginate, silver pectate) readily changed into silver mirrors. When silver alginate films were photolysed at 77 K, a broad absorption band below 600 nm and a small peak near 335 nm, probably due to silver clusters, appeared. In this method, silver atoms in the various aggregation states (atoms, clusters, colloids, bulk metal) can be formed by changing photolysis conditions. The preparation of matrix-supported silver films reported by other research groups has been reviewed briefly." @default.
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- W2020100143 date "1992-10-01" @default.
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- W2020100143 title "Formation of silver metal films by photolysis of silver salts of high molecular weight carboxylic acids" @default.
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- W2020100143 doi "https://doi.org/10.1016/0040-6090(92)90909-u" @default.
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