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• W2020110106 endingPage "121" @default.
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• W2020110106 abstract "Recently characterized intermetallic phases of the alkali metals and the heaviest icosogens In and Tl contain unusual hypoelectronic icosogen deltahedra having from 5 to 11 vertices. In these deltahedra the apparent electron deficiency is relieved by a distortion consisting of flattening selected vertices to allow participation of vertex d orbitals in addition to the usual sp3 valence orbital manifold. The shapes of these In and Tl deltahedra suggest that such flattening occurs preferentially at degree 4 vertices in accord with the four-fold symmetry of the relevant (n−1) d orbitals (e.g. d(x2−y2)). The prevalence of globally delocalized flattened 10- and 11-vertex In deltahedra in phases such as K3In10Zn and K8In11 can be related to the strategic location of their degree 4 vertices, all of which are subject to flattening with retention of the symmetry of the undistorted deltahedron. A greater variety of structures are found in the Tl deltahedra where symmetry breaking of octahedral and tricapped trigonal bipyramidal Tl clusters can occur through selective flattening of degree 4 vertices of Tl66− in KTl and Tl99− in Na2K21Tl19, respectively. In addition, a variety of regular icosahedral Tl12 clusters are known such as the Tl(Tl12)10− anions in Na4M6Tl13 (M = K, Rb, Cs), the Tl(Tl12)11− anion in Na3K8Tl13, and the Na(Tl12)13− anion in Na15K6Tl18H in which the apparent deficiencies are relieved by introduction of interstitial atoms (Tl or Na) rather than flattening in accord with the absence of degree 4 vertices in the regular icosahedron." @default.
• W2020110106 created "2016-06-24" @default.
• W2020110106 creator A5077383248 @default.
• W2020110106 date "1996-11-01" @default.
• W2020110106 modified "2023-09-24" @default.
• W2020110106 title "Metal cluster topology 18. Flattening of hypoelectronic indium and thallium deltahedra in intermetallic phases containing alkali metals" @default.
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• W2020110106 doi "https://doi.org/10.1016/s0020-1693(96)05304-2" @default.
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