FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2020113269> ?p ?o ?g. }

• W2020113269 endingPage "771" @default.
• W2020113269 startingPage "767" @default.
• W2020113269 abstract "The kinetics of nucleophilic aromatic substitution of three nitrothiophene derivatives in different [1-butyl-3-methylimidazolium][N3]/ionic liquid binary mixtures was studied spectrophotometrically at 298 K. Ionic liquids differing for cation structure (imidazolium or pyrrolidinium) and for size, shape, and coordination ability of the anion ([BF4−], [PF6−], [SbF6−], and [NTf2−]) were used. Furthermore, in order to have a comparison with conventional organic solvents, the target reaction was also carried out in DMF solution at increasing concentration of NaN3 or [bmim][N3]. Data collected show that the reaction occurs faster in DMF than in ionic liquid solution. Furthermore, as a consequence of the ability of all solvent media to favor the leaving group departure, a simple linear dependence of the pseudo-first-order kinetic constant from nucleophile concentration was detected. The results of this kinetic investigation once more underline that ionic liquids are able to exert peculiar effects that can be understood also considering their three-dimensional organization." @default.
• W2020113269 created "2016-06-24" @default.
• W2020113269 creator A5047757372 @default.
• W2020113269 creator A5070055086 @default.
• W2020113269 creator A5087159187 @default.
• W2020113269 date "2009-12-29" @default.
• W2020113269 modified "2023-09-23" @default.
• W2020113269 title "Aryl Azides Formation Under Mild Conditions: A Kinetic Study in Some Ionic Liquid Solutions" @default.
• W2020113269 cites W1883779550 @default.
• W2020113269 cites W191442324 @default.
• W2020113269 cites W1947131631 @default.
• W2020113269 cites W1963865044 @default.
• W2020113269 cites W1964316680 @default.
• W2020113269 cites W1973074429 @default.
• W2020113269 cites W1975118500 @default.
• W2020113269 cites W1975846436 @default.
• W2020113269 cites W1981824101 @default.
• W2020113269 cites W1984665603 @default.
• W2020113269 cites W1987175459 @default.
• W2020113269 cites W1988425692 @default.
• W2020113269 cites W1992718099 @default.
• W2020113269 cites W1993068842 @default.
• W2020113269 cites W1997848165 @default.
• W2020113269 cites W1999583803 @default.
• W2020113269 cites W2006750289 @default.
• W2020113269 cites W2007151950 @default.
• W2020113269 cites W2009640104 @default.
• W2020113269 cites W2010423861 @default.
• W2020113269 cites W2012429772 @default.
• W2020113269 cites W2014262823 @default.
• W2020113269 cites W2017330999 @default.
• W2020113269 cites W2028356541 @default.
• W2020113269 cites W2029807337 @default.
• W2020113269 cites W2030155537 @default.
• W2020113269 cites W2031017882 @default.
• W2020113269 cites W2032338320 @default.
• W2020113269 cites W2037894985 @default.
• W2020113269 cites W2039639599 @default.
• W2020113269 cites W2046797741 @default.
• W2020113269 cites W2048032631 @default.
• W2020113269 cites W2052973400 @default.
• W2020113269 cites W2055131312 @default.
• W2020113269 cites W2055596592 @default.
• W2020113269 cites W2055914734 @default.
• W2020113269 cites W2057105206 @default.
• W2020113269 cites W2059160426 @default.
• W2020113269 cites W2060807540 @default.
• W2020113269 cites W2062689765 @default.
• W2020113269 cites W2063618473 @default.
• W2020113269 cites W2064694706 @default.
• W2020113269 cites W2066963193 @default.
• W2020113269 cites W2069009149 @default.
• W2020113269 cites W2069652976 @default.
• W2020113269 cites W2073776296 @default.
• W2020113269 cites W2076012592 @default.
• W2020113269 cites W2079226464 @default.
• W2020113269 cites W2079726351 @default.
• W2020113269 cites W2082320564 @default.
• W2020113269 cites W2083564032 @default.
• W2020113269 cites W2085126706 @default.
• W2020113269 cites W2086713708 @default.
• W2020113269 cites W2089049959 @default.
• W2020113269 cites W2090391132 @default.
• W2020113269 cites W2093985678 @default.
• W2020113269 cites W2095500543 @default.
• W2020113269 cites W2102532311 @default.
• W2020113269 cites W2106133974 @default.
• W2020113269 cites W2106806817 @default.
• W2020113269 cites W2107547314 @default.
• W2020113269 cites W2108194501 @default.
• W2020113269 cites W2115768460 @default.
• W2020113269 cites W2116440372 @default.
• W2020113269 cites W2118325245 @default.
• W2020113269 cites W2118694576 @default.
• W2020113269 cites W2125662330 @default.
• W2020113269 cites W2129299583 @default.
• W2020113269 cites W2133180110 @default.
• W2020113269 cites W2134018453 @default.
• W2020113269 cites W2143765231 @default.
• W2020113269 cites W2147803107 @default.
• W2020113269 cites W2164703096 @default.
• W2020113269 cites W2167090368 @default.
• W2020113269 cites W2171084577 @default.
• W2020113269 cites W2174203611 @default.
• W2020113269 cites W2317582768 @default.
• W2020113269 cites W2949599623 @default.
• W2020113269 cites W2951414334 @default.
• W2020113269 cites W2952483443 @default.
• W2020113269 cites W3036442760 @default.
• W2020113269 cites W4248104288 @default.
• W2020113269 cites W583380930 @default.
• W2020113269 cites W809369987 @default.
• W2020113269 cites W1982446093 @default.
• W2020113269 doi "https://doi.org/10.1021/jo9022952" @default.
• W2020113269 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20039644" @default.
• W2020113269 hasPublicationYear "2009" @default.
• W2020113269 type Work @default.
• W2020113269 sameAs 2020113269 @default.

• next