FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2020116325> ?p ?o ?g. }

• W2020116325 endingPage "1471" @default.
• W2020116325 startingPage "1461" @default.
• W2020116325 abstract "Abstract The novel coordination compound [Cu I 12 (C 16 H 16 N 4 ) 6 ] · 8DMAc, ( 2 ), (DMAc = N, N ‐dimethylacetamide) was prepared in solvothermal or microwave assisted reaction. It contains four metallamacrocyclic trinuclear copper(I) pyrazolate coordination units, which occupy four (opposite) faces of an imaginary metallosupramolecular octahedron. Six (4,4′‐(1,2‐phenylene)bis(3,5‐dimethylpyrazol‐1‐ide) ligands (L 1 2– ) are placed at the corners of the octahedron. Crystals of the free ligand H 2 L 1 [1,2‐bis(3,5‐dimethyl‐ 1H ‐pyrazol‐4‐yl)benzene, ( 1 )], and [Cu I 12 (C 16 H 16 N 4 ) 6 ] · 8DMAc ( 2 ), were characterized by single‐crystal X‐ray structure analyses. Lingand 1 crystallizes in the monoclinic crystal system, with: a = 9.0118(9), b = 14.0075(11), c = 11.7484(11) Å, β = 104.945(5)°, V = 1432.9(2) Å 3 , space group P 2 1 / c (no. 14). Compound 2 crystallizes in the tetragonal system, with: a = b = 19.506(5), c = 42.888(5) Å, V = 16318(6) Å 3 , space group I 4 1 / amd (no. 141). Compound 2 represents a porous structure, where each metallosupramolecular octahedron encloses a solvent‐filled cavity of 889 Å 3 (accounting for 6 DMAc molecules, 21.8 % of the cell volume). The incomplete crystal packing arrangement of adjacent [Cu I 12 (C 16 H 16 N 4 ) 6 ] moieties in addition leads to solvent‐filled interstitial voids accounting to 8.1 % of the cell volume. Removing solvent molecules in vacuo is accompanied by reversible structural changes, leading to a partial loss of porosity, as revealed by Ar‐BET sorption analysis. Compounds 1 and 2 were further characterized by elemental and thermogravimetric analysis, X‐ray powder diffraction, FTIR‐, UV/Vis‐ and fluorescence spectroscopy. Preliminary results on the activation of molecular oxygen by compound 2 are presented." @default.
• W2020116325 created "2016-06-24" @default.
• W2020116325 creator A5019232038 @default.
• W2020116325 creator A5034788797 @default.
• W2020116325 creator A5039990791 @default.
• W2020116325 creator A5069875978 @default.
• W2020116325 creator A5084435572 @default.
• W2020116325 creator A5091881096 @default.
• W2020116325 date "2013-05-15" @default.
• W2020116325 modified "2023-10-16" @default.
• W2020116325 title "A Metallosupramolecular Octahedron Assembled from Twelve Copper(I) Metal Ions and Six 4,4′‐(1,2‐Phenylene)bis(3,5‐dimethylpyrazol‐1‐ide) Ligands" @default.
• W2020116325 cites W1897664089 @default.
• W2020116325 cites W1965332142 @default.
• W2020116325 cites W1968790915 @default.
• W2020116325 cites W1969635440 @default.
• W2020116325 cites W1977961375 @default.
• W2020116325 cites W1978225236 @default.
• W2020116325 cites W1980828677 @default.
• W2020116325 cites W1981763423 @default.
• W2020116325 cites W1990334208 @default.
• W2020116325 cites W1992165820 @default.
• W2020116325 cites W1993126648 @default.
• W2020116325 cites W1995069077 @default.
• W2020116325 cites W1999925216 @default.
• W2020116325 cites W1999990975 @default.
• W2020116325 cites W2003686983 @default.
• W2020116325 cites W2004825920 @default.
• W2020116325 cites W2009587949 @default.
• W2020116325 cites W2011879584 @default.
• W2020116325 cites W2014049560 @default.
• W2020116325 cites W2015308769 @default.
• W2020116325 cites W2016614732 @default.
• W2020116325 cites W2032707250 @default.
• W2020116325 cites W2041721340 @default.
• W2020116325 cites W2049513555 @default.
• W2020116325 cites W2051277759 @default.
• W2020116325 cites W2053700726 @default.
• W2020116325 cites W2053971567 @default.
• W2020116325 cites W2058206851 @default.
• W2020116325 cites W2065614463 @default.
• W2020116325 cites W2070989955 @default.
• W2020116325 cites W2071398165 @default.
• W2020116325 cites W2075308715 @default.
• W2020116325 cites W2078877422 @default.
• W2020116325 cites W2083322390 @default.
• W2020116325 cites W2084212938 @default.
• W2020116325 cites W2085680890 @default.
• W2020116325 cites W2087571702 @default.
• W2020116325 cites W2088855181 @default.
• W2020116325 cites W2097888967 @default.
• W2020116325 cites W2108633598 @default.
• W2020116325 cites W2113568413 @default.
• W2020116325 cites W2122793879 @default.
• W2020116325 cites W2123771203 @default.
• W2020116325 cites W2131888035 @default.
• W2020116325 cites W2140006351 @default.
• W2020116325 cites W2142699453 @default.
• W2020116325 cites W2151150359 @default.
• W2020116325 cites W2166689829 @default.
• W2020116325 cites W2168637788 @default.
• W2020116325 cites W2323231721 @default.
• W2020116325 cites W2332220389 @default.
• W2020116325 cites W4293225844 @default.
• W2020116325 doi "https://doi.org/10.1002/zaac.201300094" @default.
• W2020116325 hasPublicationYear "2013" @default.
• W2020116325 type Work @default.
• W2020116325 sameAs 2020116325 @default.
• W2020116325 citedByCount "15" @default.
• W2020116325 countsByYear W20201163252016 @default.
• W2020116325 countsByYear W20201163252017 @default.
• W2020116325 countsByYear W20201163252019 @default.
• W2020116325 countsByYear W20201163252020 @default.
• W2020116325 countsByYear W20201163252021 @default.
• W2020116325 countsByYear W20201163252022 @default.
• W2020116325 crossrefType "journal-article" @default.
• W2020116325 hasAuthorship W2020116325A5019232038 @default.
• W2020116325 hasAuthorship W2020116325A5034788797 @default.
• W2020116325 hasAuthorship W2020116325A5039990791 @default.
• W2020116325 hasAuthorship W2020116325A5069875978 @default.
• W2020116325 hasAuthorship W2020116325A5084435572 @default.
• W2020116325 hasAuthorship W2020116325A5091881096 @default.
• W2020116325 hasBestOaLocation W20201163252 @default.
• W2020116325 hasConcept C115624301 @default.
• W2020116325 hasConcept C116569031 @default.
• W2020116325 hasConcept C170493617 @default.
• W2020116325 hasConcept C170751736 @default.
• W2020116325 hasConcept C178790620 @default.
• W2020116325 hasConcept C185592680 @default.
• W2020116325 hasConcept C198819137 @default.
• W2020116325 hasConcept C2777691172 @default.
• W2020116325 hasConcept C2777921878 @default.
• W2020116325 hasConcept C2780471494 @default.
• W2020116325 hasConcept C32909587 @default.
• W2020116325 hasConcept C39297587 @default.
• W2020116325 hasConcept C544778455 @default.
• W2020116325 hasConcept C55493867 @default.
• W2020116325 hasConcept C61276311 @default.
• W2020116325 hasConcept C71240020 @default.

• next