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- W2020117868 abstract "The effect of n-amyl alcohol on the electrode reaction rate of the V2+/V3+ and Cr2+/Cr3+ systems in 0.5 M H2SO4 was investigated. Inhibition effects were measured over the whole adsorption region of n-amyl alcohol and the conclusion was reached that the mode of inhibition in these redox systems was the same. The rate constant of the V2+/V3+ system at potentials near the e.c.m. in the presence of the alcohol can be expressed as ko=(1-0)nk0=O at lower coverages. This result suggests that the electrode reaction takes place only at the time when each n water molecule aggregate is replaced by each of the electro-active ions at the electrode; that is, the “blocking effect” predominates at low coverages. The rate constant at the covered surface was too small to be considered. The number of water molecules displaced by electroactive ions at one time was n=6.4 (134 Å2 per hexaquovanadic ion), which is reasonable for the hexaquovanadic ion. At higher surface coverages, the “sieve effect” predominates and the rate constant approaches the limiting value." @default.
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- W2020117868 date "1971-09-01" @default.
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- W2020117868 title "Effect of n-amyl alcohol on the electrode kinetics of the V(II)/V(III) and Cr(II)/Cr(III) systems" @default.
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- W2020117868 doi "https://doi.org/10.1016/s0022-0728(71)80191-2" @default.
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