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- W2020118479 abstract "Abstract Synthesis, crystal structure as well as IR‐ and Raman‐spectroscopic properties of the new ternary azidoaurates(III) A [Au(N 3 ) 4 ] ( A = K, Rb, Cs) are reported. The translucent orange‐red compounds were prepared by reaction of the respective binary azides with HAuCl 4 in aqueous solutions at room temperature. The crystal structures determined by single crystal X‐ray diffraction methods are monoclinic ( C 2/ c (No. 15), K/Rb/Cs[Au(N 3 ) 4 ]: a = 1049.30(9) pm / 1033.93(10) pm / 1011.9(8) pm, b = 1047.52(8) pm / 1064.20(11) pm / 1093.8(8) pm, c = 776.97(7) pm / 809.79(8) pm / 858.4(6) pm, β = 91.220(5)° / 90.322(5)° / 92.72(5)°) and provide the first examples for azidoaurates with mono‐atomic cations. The unusual reduction of the lattice parameter a with increasing cation size in the isotypic series is discussed in detail. IR‐ and Raman‐spectroscopic measurements show strongly covalent gold‐nitrogen contacts, a bonding situation which is further supported by quantum chemical calculations and ELF‐analyses." @default.
- W2020118479 created "2016-06-24" @default.
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- W2020118479 date "2006-07-31" @default.
- W2020118479 modified "2023-09-26" @default.
- W2020118479 title "Azidoaurates of the Alkali Metals" @default.
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- W2020118479 doi "https://doi.org/10.1002/zaac.200600062" @default.
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