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- W2020122014 abstract "The complexes MeAsH2 · M(CO)n with M(CO)n Cr(CO)5, W(CO)5, Fe(CO)4, Fe(CO) (NO)2, Co(CO)2NO, and Ni(CO)3 are so unstable that only MeAsH2 · W(CO)5 could be isolated in pure state. They decompose with loss of CO and H2 to form oligomeric compounds of low solubility. From MeAsH2 · Fe(CO)4 the cubane-like oligomer [MeAsFe(CO)3]4 is isolated and identified by crystal structure analysis. MeAsH2 · Fe(CO)4 and Co2(CO)8 or C3H5Co(CO)3 formed a methyl-arsinidene cluster MeAsFeCo2 (CO)9. Die Komplexe meAsH2 · M(CO)η mit M(CO)η Cr(CO)5, Mo(CO)5, W(CO)5, Fe(CO)4, Fe(CO)(NO)2, Co(CO)2NO und Ni (CO)3 sind so instabil, dass nur MeAsH2 · W(CO)5 in reiner Form isoliert werden konte. Sie zersetzen sich unter Verlust von CO und Bildung von oligomeren Produkten niedriger Löslichkeit. Aus MeAsH2 · Fe(CO)4 wurde das Cuban-artige Oligomer [MeAsFe-(CO)3]4 isoliert und durch eine Kristallstrukturanalyse identifiziert. MeAsH2 · Fe(CO)4 und Co2(CO)8 oder C3H5Co(CO)3 bildeten den Methylarsiniden-Cluster MeAsFeCo2 (CO)9." @default.
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- W2020122014 date "1981-06-01" @default.
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- W2020122014 title "Methylarsin-und methylarsiniden-metallcarbonyle" @default.
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- W2020122014 doi "https://doi.org/10.1016/s0022-328x(00)93946-9" @default.
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