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• W2020132018 abstract "Surface and thermodynamic properties of well-purified N-dodecylpyridinium bromide and N-dodecylpyridinium chloride in aqueous solution and in solutions of the corresponding sodium halides of 0.1 M and 0.5 M total ionic strength have been measured at 10, 25 and 40°C. Properties measured are critical micelle concentration (cmc), maximum surface excess concentration and minimum area per molecule at the aqueous solution—air interface, efficiency and effectiveness of surface tension reduction, and standard thermodynamic parameters of micellization and of adsorption. N-Dodecylpyridinium bromide is somewhat more surface-active than the corresponding chloride. The difference appears to be due to the greater degree of hydration of the chloride ion compared to the bromide. The entropy factor is the major contributor to the free energy of both micellization and adsorption. Micellization appears to involve more dehydration of the counter-ion than adsorption at the aqueous solution-air interface." @default.
• W2020132018 created "2016-06-24" @default.
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• W2020132018 date "1982-10-01" @default.
• W2020132018 modified "2023-09-27" @default.
• W2020132018 title "Relationship of structure to properties in surfactants. 11. surface and thermodynamic properties of N-dodecyl-pyridinium bromide and chloride" @default.
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• W2020132018 doi "https://doi.org/10.1016/0166-6622(82)80071-1" @default.
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