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• W2020133741 abstract "Thiocyanate assembly is shown to be an effective method for assembling thiolate structures on platinum, silver, and gold. The assemblies were studied by infrared reflection spectroscopy and X-ray photoelectron spectroscopy (XPS). Two cyanide species were identified on the surfaces: the first corresponding to adsorbed cyanide and the second to a form commonly seen as an intermediate during cyanide etching of metals. The presence of the second species supports the theory that cyanide is leaving the surface as M(CN)x, resulting in a thiolate monolayer. Comparison of thiocyanate assemblies on evaporated gold and silver to those on template-stripped gold demonstrates the integral role of surface morphology in the expulsion of (CN)ads from the surface of the metals." @default.
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• W2020133741 creator A5042792059 @default.
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• W2020133741 date "2005-10-19" @default.
• W2020133741 modified "2023-10-03" @default.
• W2020133741 title "Mechanistic Implications of the Assembly of Organic Thiocyanates on Precious Metals" @default.
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• W2020133741 doi "https://doi.org/10.1021/cm0510357" @default.
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