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- W2020136006 abstract "A novel self-assembling molecule with coplanar anthraquinonyl and anthryl moieties linked by an acetylenic unit has been designed and synthesized as an electron acceptor for efficient photocurrent generation. The high-resolution scanning tunneling microscopy (STM) images showed that the self-assembled monolayer (SAM) of this molecule forms highly ordered two-dimensional (2D) arrays on Au(111) with an oblique lattice and graphite-like stacking at room temperature. The electrochemical study of this molecule and its SAM on Au showed reversible characteristics. The SAMs generated by co-assembling this acceptor with an oligo(pyrrolethiophene) donor show very promising photoelectrochemical properties. The amount of photocurrent generated (up to 1425 nA/cm2, 23.1% of quantum yield) under the illumination of 360 nm light is comparable to that obtained from using a C60-based molecule as the electron acceptor (1700 nA/cm2). This result demonstrates the feasibility of using anthraquinone-anthrylacetylene-thiol linked molecule as an efficient electron acceptor for constructing a monochromatic light-to-current molecular converter." @default.
- W2020136006 created "2016-06-24" @default.
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- W2020136006 date "2005-05-01" @default.
- W2020136006 modified "2023-09-26" @default.
- W2020136006 title "Thiol-Linked Anthraquinone Anthryl Acetylene Molecule: Synthesis, Self-assembly, and Photoelectrochemical Properties" @default.
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- W2020136006 doi "https://doi.org/10.1021/cm050243w" @default.
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