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- W2020142244 abstract "The morphology transition due to midblock swelling with low-molecular-weight homopolymer polystyrene of an ABA-type triblock copolymer polyparamethylstyrene-block-polystyrene-block-polyparamethylstyrene at the buried silicon substrate interface is studied as a function of different substrate surface treatments. With grazing incidence small-angle neutron scattering (GISANS), high interface sensitivity is reached. The powderlike oriented lamellar structure in the bulk becomes oriented along the surface normal in the vicinity of the substrate. A transition of the lamellar into a cylinder phase at the polymer-silicon interface is probed with GISANS. The transition is induced by the addition of the homopolymer, but the modification of the short-ranged interface potential of the substrate influences the amount of homopolymer that is necessary for this transition. Without and with 0.1 vol % added homopolymer, the lateral spacing is stretched at the interface as compared to the bulk whereas for a higher added amount of homopolymer no stretching occurs." @default.
- W2020142244 created "2016-06-24" @default.
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- W2020142244 date "2008-10-28" @default.
- W2020142244 modified "2023-09-23" @default.
- W2020142244 title "Interface-Induced Morphology Transition in Triblock Copolymer Films Swollen with Low-Molecular-Weight Homopolymer" @default.
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- W2020142244 doi "https://doi.org/10.1021/la802471p" @default.
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