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• W2020145320 abstract "We report the preparation and characterization of waterborne polyurethane (WBPU)/hydroxyapatite (HAp) nanocomposites through in situ polymerization from functionalized HAp. The HAp nanoparticles (HAp NPs) were urethanated with 3-isocyanatemethyl-3,5,5-trimethyl-cyclohexylisocyanate (isophorone diisocyanate) to obtain grafted HAp NPs containing isocyanate groups (HAp-g-NCO) as crosslinkers and then the HAp-g-NCO is further polymerized with WBPU monomers to form the WBPU/HAp nanocomposites. The HAp NPs were homogeneously dispersed in the polyurethane matrix at low loading levels (⩽2.0 wt%), thus the mechanical strength and the elongation at break of the WBPU/HAp nanocomposites were significantly improved. Thermal stability and water resistance of the WBPU/HAp nanocomposites are also enhanced. These results suggest that the WBPU/HAp nanocomposites prepared by in situ polymerization hold the potential as new materials with improved mechanical properties, thermal stability and water resistance." @default.
• W2020145320 created "2016-06-24" @default.
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• W2020145320 date "2008-07-01" @default.
• W2020145320 modified "2023-09-29" @default.
• W2020145320 title "Preparation of waterborne polyurethane nanocomposites: Polymerization from functionalized hydroxyapatite" @default.
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• W2020145320 doi "https://doi.org/10.1016/j.eurpolymj.2008.04.029" @default.
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