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- W2020145718 abstract "The electrocatalytic behaviour of Prussian blue towards thiol oxidation was thoroughly investigated. Cyclic voltammetry experiments performed in thiol solution showed the classical shape of a mediated redox system. The current due to thiol-mediated oxidation was then evaluated in batch amperometric mode at +200 mV vs. Ag|AgCl. Many thiocompounds were investigated and their different reactivities were discussed. Thiocholine and cysteamine were found to give the best results in terms of LOD (i.e., 5 × 10−6, 10−6 mol l−1, respectively) and linear range (5 × 10−6–5 × 10−4, 10−6–10−4 mol l−1, respectively). Two applications are also proposed, one involving the measurement of thiocholine as a mean for pesticide detection, and the other being an electrochemical alternative to Ellman’s test for total thiol estimation." @default.
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- W2020145718 date "2004-03-01" @default.
- W2020145718 modified "2023-09-23" @default.
- W2020145718 title "Characterisation of Prussian blue modified screen-printed electrodes for thiol detection" @default.
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- W2020145718 doi "https://doi.org/10.1016/j.jelechem.2003.09.016" @default.
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