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• W2020148319 abstract "Electrically conductive composites based on epoxy resin, anhydride hardener and polyaniline (PANI) as conductive filler have been formulated and characterized. Standard PANI (Pani) and PANI/clay (PANICN) nanofillers were used to study the impact of filler morphology on the electrical properties of composites. Clay was used as a nanostructured template to increase the PANI aspect ratio (ratio of length to diameter or thickness). The use of PANICN reduces the electrical percolation threshold of composites from 4.5 vol.% to 1.3 vol.%. Moreover, the conductivity of composites containing PANICN is improved to values superior to 10−3 S/cm. The effects of reagents and curing conditions were also evaluated. It was demonstrated that a classical alkaline curing accelerator, such as imidazole, exhibits chemical incompatibilities with the PANI conductive form, resulting in less conductive composites. Substituting the classical alkaline curing accelerator with a cationic accelerator, such as a Lewis acid, is a promising alternative to obtain conductive epoxy composites with a low content of PANI." @default.
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• W2020148319 date "2012-05-01" @default.
• W2020148319 modified "2023-10-16" @default.
• W2020148319 title "Polyaniline/clay as nanostructured conductive filler for electrically conductive epoxy composites. Influence of filler morphology, chemical nature of reagents, and curing conditions on composite conductivity" @default.
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• W2020148319 doi "https://doi.org/10.1016/j.synthmet.2012.02.011" @default.
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