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- W2020148995 abstract "Abstract In this study, the high-pressure phase behavior of poly[ p -decyl(oxy, thio, sulfonyl)methyl styrene] and poly[ p -perfluorooctyl-ethylene(oxy, thio, sulfonyl)methyl styrene] in supercritical solvents comprised of carbon dioxide (CO 2 ) and dimethyl ether (DME) were examined. When the poly[ p -perfluorooctyl-ethylene(oxy, thio, sulfonyl)methyl styrene] + CO 2 systems were evaluated, cloud-point pressures were obtained at temperatures ranging from 60 to 180 °C and pressures of up to 1300 bar. In addition, the poly[ p -perfluorooctyl-ethylene(oxy, thio, sulfonyl)methyl styrene] + DME mixtures dissolved at temperatures under 180 °C and pressures under 200 bar, but the poly[ p -decyl(oxy, thio, sulfonyl)methyl styrene] + CO 2 mixtures did not dissolve, even at 230 °C and 2800 bar. However, the poly[ p -decyl(oxy, thio, sulfonyl)methyl styrene] + DME mixtures readily dissolved at temperatures and pressures under 180 °C and 200 bar, respectively. Furthermore, the cloud-point curves for the poly( p -decyl sulfonyl methyl styrene) + DME mixtures with 15.6, 44.3 and 56.4 wt% CO 2 changed the P – T curve from a lower critical solution temperature (LCST) type to an upper critical solution temperature (UCST) type at increased CO 2 concentrations." @default.
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- W2020148995 date "2008-11-01" @default.
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- W2020148995 title "Phase behavior of a ternary system of poly[p-perfluorooctyl-ethylene(oxy, thio, sulfonyl)methyl styrene] and poly[p-decyl(oxy, thio, sulfonyl)methyl styrene] in supercritical solvents" @default.
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- W2020148995 doi "https://doi.org/10.1016/j.supflu.2008.06.003" @default.
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