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- W2020172875 abstract "It is shown that thin layers of platinum and ruthenium on mercury behave differently from nuclei of the same metals grown on a carbon substrate. The mechanism of hydrogen evolution is controlled by the direct discharge of H+ in the case of platinum and ruthenium on mercury, the relative current densities into edge and top of the two dimensional layers being about 100:1. In contrast, the hydrogen evolution reaction on platinum is controlled under all conditions by diffusion of molecular hydrogen. The reaction on ruthenium, at which the coverage by H is lower than platinum, appears to be controlled by H·+H++e→H2" @default.
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- W2020172875 title "Catalytic hydrogen evolution on ruthenium and platinum nuclei" @default.
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- W2020172875 doi "https://doi.org/10.1016/s0022-0728(69)80006-9" @default.
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