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• W2020185402 abstract "Abstract The influence of aqueous solution pD on stereoselective complexation of N ‐benzyloxycarbonylaminophosphonic acids with α‐cyclodextrin was investigated by means of nuclear magnetic resonance spectroscopy. The highest enantiodiscrimination was achieved at pD close to the p K a of less acidic hydroxyl group of the phosphonic moiety of analytes (6.5–7.5). This effect results from the stereoselective differentiation of p K a (up to 0.28 pD unit) upon complexation with applied chemical shift reagent. Moreover, analysis of 2D‐ROESY spectra proved that the host–guest inclusion mode is strongly influenced by pD. Chirality, 2007. © 2007 Wiley‐Liss, Inc." @default.
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• W2020185402 date "2007-07-30" @default.
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• W2020185402 title "Analysis of pD-Dependent complexation ofN-benzyloxycarbonylaminophosphonic acids by α-cyclodextrin. Enantiodifferentiation of phosphonic acid pKa values" @default.
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• W2020185402 doi "https://doi.org/10.1002/chir.20450" @default.
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