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- W2020188930 abstract "Abstract The oxidation of γ-irradiated, low density PE film has been studied by measurement of the induction period in absorption of oxygen in the temperature range of 100–180°. The apparent energies of activation for oxidation of unirradiated and irradiated PE were obtained. On the basis of the results it is suggested that degassed films of thickness greater than 20 μm contain residual oxygen, which during irradiation react with the radicals produced, forming hydroperoxides. The hydroperoxides lower the resistance of the polyethylene to thermal oxidation. Solution on a computer of a set of differential equations based on a proposed reaction scheme, and iodometric measurements of the concentration of active oxygen in irradiated PE, support this hypothesis." @default.
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- W2020188930 date "1977-01-01" @default.
- W2020188930 modified "2023-09-25" @default.
- W2020188930 title "The effect of hydroperoxides on the thermal-oxidative stability of γ-irradiated polyethylene film" @default.
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- W2020188930 doi "https://doi.org/10.1016/0032-3950(77)90404-x" @default.
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