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- W2020189895 abstract "Perovskite-type (La0.1Ca0.9)(Mn1−xTix)O3(0 ≤ × ≤ 0.9) has the orthorhombic GdFeO3-type structure with the space groupPnma. With increasingx, the average (Mn, Ti)–O distance increases linearly and the average angles for (Mn, Ti)–O–(Mn, Ti) decrease slightly. The electrical resistivity (ρ) of all manganates was measured in the temperature range from 10 to 953 K. All manganates aren-type semiconductors at low temperature. At high temperature, the manganates exhibit a metal–insulator transition in the range 0 ≤x≤ 0.3.dρ/dTin the metallic region depends on the composition. From these results, it is considered that the Ti4+ion makes the cation–anion–cation overlap integrals (Δπcacand Δσcac) weaken." @default.
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- W2020189895 date "1996-11-01" @default.
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- W2020189895 title "Role of Tetravalent Ion in Metal–Insulator Transition in (La0.1Ca0.9)(Mn1−Ti )O3" @default.
- W2020189895 doi "https://doi.org/10.1006/jssc.1996.0334" @default.
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