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- W2020194741 abstract "Abstract The hydrogen transport through a LaNi 4.7 Al 0.3 H x porous electrode in the coexistence of two hydrogen-poor phase α-LaNi 4.7 Al 0.3 H x and hydrogen-rich phase β-LaNi 4.7 Al 0.3 H x has been investigated during the hydrogen discharging from the electrode by analysing current decay transients supplemented by a cyclic polarization curve and open-circuit potential transients. From the occurrence of three-staged current decay transients, the β-LaNi 4.7 Al 0.3 H x patches were sporadically embedded in the α-phase matrix during the hydrogen charging into the electrode at the overpotentials between −0.01 and −0.03 V (RHE) and the β-LaNi 4.7 Al 0.3 H x layer was completely embedded in matrix below −0.03 V (RHE). The hydrogen transport through the spherical symmetric LaNi 4.7 Al 0.3 H x particle proceeded by the same mechanism of the “up-hill diffusion” coupled with interface-controlled phase boundary movement, as did the hydrogen transport through the plane symmetric Pd foil electrode. The current decay transient technique employed in this work proved to be a more informative approach to evaluation of the charge-discharge performance of the metal hydride electrode in practical use of the nickel/metal hydride secondary battery." @default.
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- W2020194741 title "Hydrogen transport through LaNi4.7Al0.3Hx porous electrode in the coexistence of two hydride phases (α- and β-phases): current transient analysis" @default.
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- W2020194741 doi "https://doi.org/10.1016/s0013-4686(97)00101-1" @default.
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