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- W2020199394 abstract "The microstructure and chemistry of a Ti-rich (Ba, Sr)TiO3 film with 53.4% Ti deposited on a Pt/SiO2/Si substrate by metallorganic chemical-vapor deposition was studied using high-resolution transmission electron microscopy and elemental mapping in electron energy-loss spectroscopy. We established that the Ti/Ba ratio at all the grain boundaries in this film is significantly higher than that in the grain interiors. Structural images revealed the presence of disordered amorphous-like regions at some of the grain boundaries and triple junctions; these regions were tentatively identified as those having the highest Ti/Ba ratio in the chemical maps. Analysis of the electron energy-loss near-edge structure for the O–K edge indicated an increased titanium-to-oxygen coordination at the grain boundaries. No second phase was detected at the (Ba, Sr)TiO3/Pt interface." @default.
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- W2020199394 date "1999-08-30" @default.
- W2020199394 modified "2023-09-23" @default.
- W2020199394 title "Accommodation of excess Ti in a (Ba, Sr)TiO3 thin film with 53.4% Ti grown on Pt/SiO2/Si by metalorganic chemical-vapor deposition" @default.
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- W2020199394 doi "https://doi.org/10.1063/1.124674" @default.
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