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- W2020216074 abstract "The kinetics of the title reaction have been investigated at 298 K using time‐resolved long‐pathlength absorption spectroscopy to monitor the temporal behavior of IO following 351‐nm laser flash photolysis of NO 2 /I 2 /CH 3 SCH 3 (DMS)/N 2 /O 2 mixtures. We obtain an upper limit bimolecular rate constant for the IO+DMS reaction of 3.5×0 −14 cm 3 molecule −1 s −1 ; this upper limit is nearly 3 orders of magnitude slower than two previously reported measurements. Our results suggest that coupling of the marine sulfur and iodine cycles via the IO+DMS reaction is negligible." @default.
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- W2020216074 modified "2023-09-24" @default.
- W2020216074 title "Rate of reaction of IO radicals with dimethylsulfide" @default.
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- W2020216074 doi "https://doi.org/10.1029/jd095id11p18547" @default.
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