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- W2020245611 abstract "Tropone tosylhydrazone sodium salt, the precursor of the cyclic conjugated carbene (cycloheptatrienylidene), was decomposed in the presence of various cyclopentadienone derivatives to give endo- and exo-[4+2]-type adducts and benzotropylidene derivatives. The product ratios between the endo-[4+2]-type adducts and the exo-[4+2]-type adducts are considered to suggest that these addition reactions proceed via a cyclic conjugated allene (1,2,4,6-cycloheptatetraene), which is a valence-bond isomer of cycloheptatrienylidene. Upon heating, the [4+2]-type adducts gave the benzotropylidene derivatives via decarbonylation reactions followed by 1,5-hydrogen shifts." @default.
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- W2020245611 date "1985-09-01" @default.
- W2020245611 modified "2023-09-26" @default.
- W2020245611 title "Decompositions of Tropone Tosylhydrazone Sodium Salt in the Presence of Cyclopentadienone Derivatives. [4+2]-Type Cycloaddition Reactions of Cycloheptatrienylidene or 1,2,4,6-Cycloheptatetraene with Cyclopentadienone Derivatives" @default.
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- W2020245611 doi "https://doi.org/10.1246/bcsj.58.2664" @default.
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