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- W2020263893 abstract "In the Diels–Alder reaction of 1,4-dialkoxyanthracenes and maleic anhydride, which can afford syn- and anti-cycloadducts, the bridgehead methine proton of the cycloadducts has proved to be a useful probe for determining syn/anti selectivity, as supported by isolation of diastereomers, 1H NMR spectroscopy, and X-ray analysis. In the case of methoxy and propoxy substituents, a slight anti-preference was observed, on the other hand, the reaction of 1,4-bis(benzyloxy)anthracene gave a small syn-preference. Theoretical calculations of transition states of 1,4-dimethoxyanthracene and maleic anhydride showed no stereochemical preference. From UV–vis spectra, the formation of charge transfer complexes of anthracenes and maleic anhydride is possible." @default.
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- W2020263893 date "2004-07-01" @default.
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- W2020263893 title "Synthesis, Isolation, and Characterization of Diels–Alder Adducts between 1,4-Dialkoxyanthracenes and Maleic Anhydride" @default.
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