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- W2020276199 abstract "In this article, we reported the solubilities of the amino acid DL-nor-valine (VAL) at five equidistant temeratures i.e. from 15 to 35 °C in aqueous mixtures of N,N-dimethyl formamide (DMF). The Standard free energies (ΔG (i)) and entropies (ΔS (i)) of transfer of VAL from water to aqueous mixture of cationophilic dipolar aprotic DMF have been evaluated at 25 °C. The transfer of Gibbs energies (ΔG (i)) and entropies (TΔS (i)) due to the chemical effects have been obtained after elimination of cavity effect, estimated by the scaled particle theory and dipole-dipole interaction effects, computed by the used of Keesom-orientation expression. The chemical contribution of transfer energetics of DL-nor-valine (VAL) are mainly guided by the composite effects of increased dispersion interaction, basicity effect and decreased acidity, hydrogen bonding effects, hydrophilic hydration and hydrophobic hydration of aqueous DMF mixtures as compared to that of reference solvent, water." @default.
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- W2020276199 date "2014-03-26" @default.
- W2020276199 modified "2023-09-27" @default.
- W2020276199 title "Solvation Chemistry of DL-Nor-Valine in Aqueous Mixture of Dipolar AproticN,N-Dimethyl Formamide" @default.
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- W2020276199 doi "https://doi.org/10.1002/jccs.201300360" @default.
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