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- W2020285242 abstract "Orthoesterification of sucrose with 1,1-dimethoxyethene under kinetic control gave 4,6-O-methoxyethylidenesucrose in 77% crude yield. Similar orthoesterification of maltose led essentially after acetylation to 1,2,3,6,2′,3′-hexa-O-acetyl-4′-6′-O-methoxyethylidenemaltose. Analogous treatment of α,α-trehalose gave 2,3,2′,3′-tetra-O-acetyl-4,6:4′,6′-di-O-methoxyethylidene-α,α-trehalose in 47% yield. The acid-catalyzed opening of these orthoesters was studied, and these reactions were shown to give disaccharides selectively protected by acetyl groups." @default.
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- W2020285242 date "1971-10-01" @default.
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- W2020285242 title "Crystalline 2,3,4,3′,4′-penta-O-acetyl-6,1′,6′-tri-O-tosylsucrose and its reactions" @default.
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