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• W2020287429 abstract "An evaluation of the environmental impact of stressed-induced compounds, 1-penten-3-ol, (Z)-3-hexen-1-ol, and 1-penten-3-one (ethyl vinyl ketone, EVK), is presented in this paper. The removal processes considered here are the gas-phase reactions with hydroxyl (OH) radicals and photolysis in the actinic region (above 290 nm). The wavelength dependence of the gas-phase absorption cross-sections (σλ) was measured by UV−visible spectroscopy (λ = 200−390 nm). The kinetic study of the OH-reaction with pentenyl compounds has been performed as a function of temperature (T = 263−353 K) for the first time. The resulting Arrhenius expressions for the T-dependence of the OH-rate coefficient, kOH (in cm3 molecule−1 s−1 and uncertainties of ±σ), were (7.7 ± 0.8) × 10−12 exp{(606 ± 30)/T} for 1-penten-3-ol and (4.4 ± 1.4) × 10−12 exp{(507 ± 90)/T} for EVK, respectively. kOH for (Z)-3-hexen-1-ol is reported at 298 K. The experimental evidence shows that the major tropospheric removal of pentenyl compounds is the gas-phase reaction with OH radicals. However, O3 and NO3 radicals may compete with OH radicals as tropospheric sinks of (Z)-3-hexen-1-ol. Photolysis of these compounds is expected to be of minor importance in the troposphere." @default.
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• W2020287429 date "2009-02-10" @default.
• W2020287429 modified "2023-10-17" @default.
• W2020287429 title "Photooxidation of Leaf-Wound Oxygenated Compounds, 1-Penten-3-ol, (<i>Z</i>)-3-Hexen-1-ol, and 1-Penten-3-one, Initiated by OH Radicals and Sunlight" @default.
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• W2020287429 doi "https://doi.org/10.1021/es8027814" @default.
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