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- W2020287773 abstract "The stereodynamics of N-ethyl-N-tert-butylneopentylamine 2 and three similar compounds 3–5, are reported and discussed. Dynamic NMR spectroscopy yields experimental barriers to nitrogen inversion–rotation, N–tert-alkyl bond rotation and N–ethyl bond rotation for 2 of 8.1, 7.3 and 6.0 kcal mol–1, respectively, and shows that two different conformations about the latter bond are populated in the ratio 9 : 1. Molecular mechanics calculations fit well with these observations indicating which these conformations are and yielding a calculated ethyl group rotation barrier in good accord with experiment. Comparable results are obtained for the other three compounds." @default.
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- W2020287773 date "1991-01-01" @default.
- W2020287773 modified "2023-09-26" @default.
- W2020287773 title "Ethyl-group rotational barriers in hindered trialkylamines. A dynamic NMR and molecular mechanics investigation" @default.
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- W2020287773 doi "https://doi.org/10.1039/p29910001431" @default.
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