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- W2020329405 abstract "5 α -Androstane-3, 16-dione has been prepared by hydroboration and oxidation of 3 β -hydroxy-5 α -androst-16-ene. Reduction with sodium borohydride gave the 3 β , 16 β -diol. The fungus Cephalosporium aphidicola has been shown to hydroxylate 5 α -androstane-3, 16-dione predominantly at the C-6 β position with minor hydroxylation occurring at the C-7 α and C-14 α positions. In contrast hydroxylation of the 3 β , 16 β -diol took place at C-11 α . The 3 β -hydroxy-16 α , 17 α -epoxide was hydroxylated at the C-6 β position." @default.
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- W2020329405 date "1998-11-05" @default.
- W2020329405 modified "2023-09-27" @default.
- W2020329405 title "The microbiological hydroxylation of 3,16-Disubstituted androstanes by cephalosporium aphidicola" @default.
- W2020329405 doi "https://doi.org/10.1016/s0031-9422(98)00096-x" @default.
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