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- W2020350886 abstract "TlInS2xSe2(1−x) (0 ≦ x ≦ 0.25) and TlGaxIn1−xSe2 (0 ≦ x ≦ 0.3) solid solutions are studied by the methods of long-wave infrared (IR) spectroscopy. The domain of existence of an experimentally unobserved tetragonal modification of TlInS2xSe2(1−x) and TlGaxIn1−xSe2 solid solutions at (0.3)0.25 ≦ x ≦ 1 is described and the frequencies of the IR-active phonons of a tetragonal modification of TlInS2 and TlGaSe2 of A2u and Eu symmetries are determined by a virtual-crystal approximation in an isodisplacement model without adjustable parameters for intermediate compositions in the case of many oscillators.Mit Methoden der langwelligen Infrarot (IR)- Spektroskopie werden die TlInS2xSe2(1−x) (0≦x≦ ≦0,25)- and TlGaxIn1−xSe2 (0 ≦ x≦0,3)-Mischsysteme unterusucht. Der Existenzbereich einer experimentell nichtbeobachteten tetragonalen Modifikation von TlInS2xSe2(1−x)- und TlGaxIn1−xSe-Mischsystemen bei (0,3)0,25 ≦x≦1 wird beschrieben und die Frequenzen der IR-aktiven Phononen einer tetragonalen Modifikation von TIInS2 aund TlGaSe2 mit A2n- und Eu- Symmetrien werden im Rahmen einer virtuellen Kristallnaherung in einem iso-verzerrten Modell ohne anpasbare Parameter fur Zwischen-Zusammensetzungen im Fall von Mehrfachoszillatoren bestimmt." @default.
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- W2020350886 date "1990-03-01" @default.
- W2020350886 modified "2023-09-26" @default.
- W2020350886 title "Rearrangement Features of the Vibrational Spectra of TlInS2xSe2(1−x) and TlGaxIn1−xSe2 Solid Solutions" @default.
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- W2020350886 doi "https://doi.org/10.1002/pssb.2221580106" @default.
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