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- W2020351607 abstract "The IR spectra of (aroyloxymethyl)trigfluorosilanes 4-X-C6H4COOCH2)SiF(in3 (AFS) containing an intramolecular O → Si coordinate bond, have been examined in the 500-200 cm−1 region. The band near 330 cm−1 is assigned to the O → Si bond stretching vibration because of its λ sensitivity to changes in the polarity of the medium and because of its response to the nature of substituent X as well as to the formation of AFS-pyridine complexes. Normal-coordinate analysis of a model compound HCOOCH2SiF3 has been carried out. By use of a set of frequency partial derivatives by force constants a force field corresponding to the experimental frequencies and equilibrium geometry of 4-F-C6H4COOCH2SiF3 has been selected. The v(O → Si) stretching vibration is delocalized by three low-frequency motions 360, 330 and 218 cm−1. The effect of electronic and kinematic factors on the AFS vibrational spectra has been evaluated." @default.
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- W2020351607 date "1991-11-01" @default.
- W2020351607 modified "2023-09-23" @default.
- W2020351607 title "Vibrational spectra of (O → Si)-(aroyloxymethyl)trifluorosilanes" @default.
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- W2020351607 doi "https://doi.org/10.1016/0022-328x(91)80214-5" @default.
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