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- W2020353132 abstract "The synthesis and X-ray crystal structures of Y[N(SiHMe2)2]3(carbene)x (carbene = 1,3-dimethylimidazolin-2-ylidene, x = 1, 2) are described. The donor capability of the strongly nucleophilic carbene ligand is expressed in both the displacement of two THF ligands by one carbene ligand in precursor compound Y[N(SiHMe2)2]3(THF)2 and by the addition of a second carbene ligand to yield the preferred (3 + 2) trigonal bipyramidal coordination geometry. In particular, the structural data reveal that the carbene ligands affect the coordination mode of the bis(dimethylsilyl)amide counterligands by forcing them to form close β-Si−H(silylamide)−yttrium agostic contacts. According to Pearson's terminology such carbene ligands have to be classified as hard donor ligands." @default.
- W2020353132 created "2016-06-24" @default.
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- W2020353132 date "1997-02-01" @default.
- W2020353132 modified "2023-10-16" @default.
- W2020353132 title "1,3-Dimethylimidazolin-2-ylidene Carbene Donor Ligation in Lanthanide Silylamide Complexes" @default.
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- W2020353132 doi "https://doi.org/10.1021/om9607715" @default.
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