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- W2020366870 abstract "The 4-picolinium salt (C 6 H 8 N) 3 [PMo 12 O 40 ] was synthesized hydrothermally and characterized by IR spectroscopy, TG-DTA data and single-crystal X-ray diffraction. The results indicate that the compound consists of a [PMo 12 O 40 ] 3− heteropolyoxoanion and 4-picolinium cations [C 6 H 8 N] + . A supramolecular structure is formed via intermolecular hydrogen-bonding between the different structural units. Crystal data: monoclinic, space group P2 1 /c, a = 19.7004(3), b = 14.0785(2), c = 33.0209(5) Å, β = 91.3590(10)°, V = 9155.8(2) Å 3 , Z = 8, wR2 = 0.0730. (C 6 H 8 N) 3 [PMo 12 O 40 ] has a high catalytic activity for the oxidative elimination of acetone from gases as tested in a continuousflow fixed-bed micro-reactor. When the initial concentration is 5.2 gm −3 in air, and the flow rate is 3.3 mLmin −1 , 93% of the acetone is eliminated at 70 °C." @default.
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- W2020366870 date "2011-12-01" @default.
- W2020366870 modified "2023-09-22" @default.
- W2020366870 title "Crystal Structure and Catalytic Properties of (C6H8N)3[PMo12O40]" @default.
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