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- W2020378365 abstract "Abstract Separate enthalpic and entropic contributions to substituent effects on the dissociation of m -hydroxybenzoic acid in water—dimethylsulfoxide mixtures ranging from 0.0 to 0.57 mole fraction of DMSO are presented. The effect of the medium on the reaction constant is explained in terms of solute—solvent interactions. The entropy reaction constant values ϱ s of the meta -hydroxy compound are much greater than those of the meta -chloro and nitro compounds in the examined mole fraction range. For the para -hydroxy isomer only a trend of σ s and ϱ s values can be calculated. This fact is due to the electron-releasing resonance effect which overlaps and prevails over the inductive effect." @default.
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- W2020378365 date "1979-07-01" @default.
- W2020378365 modified "2023-09-24" @default.
- W2020378365 title "Enthalpic and entropic contributions to substituent effects on the ionization of meta- and para-chlorobenzoic acids in water-dimethylsulfoxide mixtures at 25°C" @default.
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- W2020378365 doi "https://doi.org/10.1016/0040-6031(79)85010-8" @default.
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