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- W2020402018 abstract "The light pulses of two emissions of the molecule XeCl, centered at 308 and 345 nm, both have decay time constants that behave in a very similar way with respect to variations in the partial pressures of xenon and HCl; this is explained by collisional coupling between the states B and C of XeCl which are at the origin of the two emissions. The identification of the different collision processes and the determination of the reaction rate constants particularly underline the occurrence of a three-body collision process between XeCl (B,C), Xe, and HCl; the rate constant is kM=(5.85±2.70)×10−5 Torr−2 ns−1. Measurements were also made of the coupling constants B→C and C→B which were found to be kBC=(2.56±1.05)×10−4 Torr−1 ns−1 and kCB=(1.45±1.05)×10−4 Torr−1 ns−1. The deduced energy gap between the two states (EB−EC=119 cm−1) is in very good agreement with the values in the literature." @default.
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- W2020402018 date "1995-01-15" @default.
- W2020402018 modified "2023-10-18" @default.
- W2020402018 title "Kinetic study of the 308 and 345 nm emissions of the molecule XeCl" @default.
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- W2020402018 doi "https://doi.org/10.1063/1.468908" @default.
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