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- W2020458834 abstract "Abstract The synthesis and properties of segmented ABA triblock and (AB) n multiblock copolymer systems with 6,6′‐disubstituted 2,2′‐bipyridine (bpy) building blocks B and poly(oxytetramethylene) soft segments A are described. The access to the disubstituted bipyridines in large scale quantities was achieved by modification of conventional synthetic routes. In the presence of copper(I) ions these polymers formed mononuclear [Cu(I)(bpy) 2 ] complexes in solution through self‐assembly. The complexed copolymers were microphase separated systems in bulk with nano to mesoscopic superstructures consisting of copper‐bpy complex aggregates in a polyether matrix. The thermal, mechanical and elastomer properties of the block copolymers varied with composition." @default.
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- W2020458834 date "1995-04-01" @default.
- W2020458834 modified "2023-10-16" @default.
- W2020458834 title "Block copolymers with bipyridine containing segments: Synthesis and self-organization by Cu(I) complexation" @default.
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- W2020458834 doi "https://doi.org/10.1002/macp.1995.021960410" @default.
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