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- W2020485148 abstract "Abstract Copper(II) complexes with bis(benzimidazol-2-yl) ligands of the type Bz(CH 2 ) n -X-(CH 2 ) n Bz (where Bz=benzimidazol-2-yl; XO, S or CH 2 ; n =1, 2) have been characterized in solution by UV-Vis and EPR spectroscopy. Mono complexes with O or S donor atom containing ligands have square-pyramidal stereochemistries, while bis complexes have pseudo-octahedral geometries with four nitrogen donors in the equatorial plane and the two heteroatoms occupying the apical positions. The mono and bis complexes with the ligand having XCH 2 and n =2 have distorted octahedral geometries with two molecules of solvents involved in the apical positions. The experimental results on the complexes with the ligand having XCH 2 and n =1 suggest that this ligand behaves as monodentate." @default.
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- W2020485148 date "1991-08-01" @default.
- W2020485148 modified "2023-09-27" @default.
- W2020485148 title "UV-Vis and EPR spectroscopic study of copper(II) complexes with bis(benzimidazol-2-yl) ligands" @default.
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