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- W2020485328 abstract "The mid-IR spectra (4000–400 cm-1) of vinyl chloride–HCl, vinyl bromide–HCl and allyl chloride–HCl mixtures, dissolved in liquefied argon at 105 K, have been examined. In all spectra, evidence was found for the existence of a 1:1 van der Waals complex. At higher concentrations of hydrogen chloride, in the spectra of the vinyl chloride–HCl mixtures, absorption bands of a 1:2 species were also observed. Using spectra recorded at several temperatures between 95 and 120 K, the complexation enthalpies of CH2CHCl·HCl and CH2CHCl·(HCl)2 were determined to be -6.5±0.2 kJ mol-1 and -10.6±0.3 kJ mol-1, respectively." @default.
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- W2020485328 title "IR spectra, relative stability and angular geometry of vinyl chloride[ndash ]HCl, vinyl bromide[ndash ]HCl and allyl chloride[ndash ]HCl van der Waals complexes observed in liquefied argon" @default.
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- W2020485328 doi "https://doi.org/10.1039/a702484c" @default.
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